Volatile Fatty Acids | Capillary Gas Chromatography (GC) - Varian GC (Type: CP-3800) with FID Detector and Varian CP 7777 Capillary Column (50m Length, 0.32 µm Diameter, 0.25mm Coating) | Qualification and quantification of lower carboxylic acids from liquid and solid samples; e.g., acetic, propionic, n- and iso-butyric, n- and iso-valeric, caproic acid |
Alcohols, Sugars | High-Performance Liquid Chromatography (HPLC) - Bischoff device with RI Detector and a. BioRad Aminex HPLC Column HPX-87H (7.8 x 300mm; part. Size: 5.0µm) and BioRad Pre-column HPX-87H b. Hyperchrome HPLC Column Repro-Gel Ca (300 x 8.0mm; part. Size: 9.0µm) | Qualification and quantification of various acids, sugars, and alcohols; e.g., DL-lactic acid, sucrose, fructose, glucose, ethanol, 1,2-propanediol, and mannitol |
TC / TN | Thermo-catalytic High-Temperature Oxidation with Analytik Jena multi N/C 2100 S | Quantification of inorganic carbon content as well as total carbon and nitrogen content in liquid samples; Quantification of total carbon content in solids |
ICP-MS | Mass Spectrometry - Perkin Elmer ICP-MS NexION 2000 | Physical standard method for qualitative and quantitative determination of elemental contents. Inorganic element analysis for mass spectrometric trace analysis of, for example, heavy metals and micronutrients |
CSB (Chemical Oxygen Demand) | Photometry - LCK 014, 514 Cuvette Test by Dr. Lange, Thermostat LT 200 – Hach Lange; LASA 20 Sensor Array Photometer by Dr. Lange | Parameter indicating the degree of organic load in a liquid, determined according to a standardized procedure. |
FOS / TAC | Titration with Metrohm tiamo 1.2, Titrando, and Sample processor | Parameter for determining the ratio of volatile organic acids (FOS) to the acid-binding capacity of the sample (TAC) |
NH4-N (Ammonium Nitrogen) | Distillation and Titration with Gerhardt Vapodest 50s | Ammonia (NH3) and ammonium (NH4+) are in equilibrium (NH3+H2ONH4++OH-). They are captured together during the analysis (distillation followed by titration). The result can be given as ammonium concentration or, only referring to nitrogen, as ammonium nitrogen. |
TKN (Kjeldahl Nitrogen) | Acid digestion with Gerhardt digestion block with Turbosog and subsequent distillation and titration with Gerhardt Vapodest 50s | Sum of organically bound nitrogen and NH4-N as a measure of unoxidized nitrogen. In contrast to TN determination (see below), this method does not capture nitrogen from nitrite and nitrate compounds. |